SAFETY DATA SHEET
Nail polish, clear
1. IDENTIFICATION
Product Identifiers
Product Name:
Nail polish, clear
Other Names:
-
Product Number(s):
EMS72180
CAS Number:
-
Recommended use of the chemical and restriction on use
Laboratory use
Company Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
Emergency Contact Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
GHS02 Flame
Flam. Liq. 2 H225 Highly flammable liquid and vapour
GHS08 Health hazard
Repr. 1B H360 May damage fertility or the unborn child.
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
Asp. Tox. 1 H304 May be fatal if swallowed and enters airways.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
STOT SE 3 H336 May cause drowsiness or dizziness.
Flam. Liq. 2 H225 Highly flammable liquid and vapour
GHS08 Health hazard
Repr. 1B H360 May damage fertility or the unborn child.
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
Asp. Tox. 1 H304 May be fatal if swallowed and enters airways.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
STOT SE 3 H336 May cause drowsiness or dizziness.
Label Elements
Signal Words
Danger
Hazard Statement(s)
Highly flammable liquid and vapour.
Causes skin irritation.
Causes serious eye irritation.
May damage fertility or the unborn child.
May cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure.
May be fatal if swallowed and enters airways.
Causes skin irritation.
Causes serious eye irritation.
May damage fertility or the unborn child.
May cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure.
May be fatal if swallowed and enters airways.
Precautionary Statement(s)
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Do not breathe dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Immediately call a poison center/doctor.
Specific treatment (see on this label).
Do NOT induce vomiting.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF exposed or concerned: Get medical advice/attention.
Call a poison center/doctor if you feel unwell.
Get medical advice/attention if you feel unwell.
Take off contaminated clothing and wash it before reuse.
If skin irritation occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
In case of fire: Use for extinction: CO₂, powder or water spray.
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Do not breathe dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Immediately call a poison center/doctor.
Specific treatment (see on this label).
Do NOT induce vomiting.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF exposed or concerned: Get medical advice/attention.
Call a poison center/doctor if you feel unwell.
Get medical advice/attention if you feel unwell.
Take off contaminated clothing and wash it before reuse.
If skin irritation occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
In case of fire: Use for extinction: CO₂, powder or water spray.
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Primary route(s) of entry
Inhalation, Skin
Human Health
Inhalation:
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Ingestion:
If swallowed: Immediately call a poison center/doctor.
Specific treatment: Do NOT induce vomiting.
Specific treatment: Do NOT induce vomiting.
Eyes:
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing
Continue rinsing
Skin:
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
Environment
Do not allow to enter sewers/ surface or ground water.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Name
CAS No.
Content (w/w)
Classification
n-butyl acetate
123-86-4
>25-≤50%
Not Available
ethyl acetate
141-78-6
>10-≤25%
Not Available
toluene
108-88-3
>10-≤25%
Not Available
Toluenesufonamide
1338-51-8
>2.5-≤10%
Not Available
dibutyl phthalate
84-74-2
>2.5-≤10%
Not Available
4. FIRST AID MEASURES
Ingestion
If symptoms persist consult doctor.
Inhalation
Supply fresh air; consult doctor in case of complaints.
Skin Contact
Generally the product does not irritate the skin.
Eye Contact
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor
Other Information
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident
5. FIREFIGHTING MEASURES
Suitable extinguishing equipment
CO₂, sand, extinguishing powder. Do not use water.
HAZCHEM
For safety reasons unsuitable extinguishing agents: Water with full jet
Special protective equipment and precautions for fire fighters
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Environmental precautions
Do not allow to enter sewers/ surface or ground water.
Methods and materials for containment and clean up
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
7. HANDLING AND STORAGE
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Keep respiratory protective device available.
Open and handle receptacle with care.
Prevent formation of aerosols
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Keep respiratory protective device available.
Conditions for safe storage
Store in cool, dry conditions in well sealed receptacles.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Standards
Material
TWA ppm
TWA mg/m3
STEL ppm
STEL mg/m3
123-86-4 n-butyl acetate
150 ppm
710 mg/m³
150 ppm
712 mg/m³
141-78-6 ethyl acetate
-
-
-
-
108-88-3 toluene
-
-
150 ppm
560 mg/m³
84-74-2 dibutyl phthalate
-
-
-
-
108-88-3 toluene
-
-
-
-
Engineering controls
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Personal protective equipment
Eye and face protection
Tightly sealed goggles
Skin protection
Protective gloves - The glove material has to be impermeable and resistant to the product/ the substance/ the preparation
Body protection
-
Respiratory protection
In case of brief exposure or low pollution use respiratory filter device
9. PHYSICAL AND CHEMICAL PROPERTIES
General information
Appearance
Clear liquid
Odour
Strong
pH
Not determined.
Vapour Pressure
at 20 °C (68 °F): 97 hPa (72.8 mm Hg)
Density
Not determined.
Boiling Point
77 °C (170.6 °F)
Melting Point
Undetermined
Solubility
Not miscible or difficult to mix
Specific Gravity of Density
Undetermined
Flash Point
-4 °C (24.8 °F)
Flammable (Explosive) Limits
Product is not explosive. However, formation of explosive air/vapour mixtures are possible.
Lower: 1.2 Vol %
Upper: 11.5 Vol %
Lower: 1.2 Vol %
Upper: 11.5 Vol %
Ignition Temperature
370 °C (698 °F) - Product is not selfigniting
Formula
Solvent content:
Organic solvents: 77.1 %
VOC content: 77.14 %
771.4 g/l / 6.44 lb/gal
Organic solvents: 77.1 %
VOC content: 77.14 %
771.4 g/l / 6.44 lb/gal
10. STABILITY AND REACTIVITY
Reactivity
No further relevant information available.
Chemical stability
Stable under normal conditions
Possibility of hazardous reactions
No dangerous reactions known.
Conditions to avoid
No further relevant information available.
Incompatible materials
No further relevant information available.
11. TOXICOLOGICAL INFORMATION
Acute effects
LD/LC50 values that are relevant for classification:
108-88-3 toluene
Oral LD50 5,000 mg/kg (rat)
Dermal LD50 12,124 mg/kg (rabbit)
Inhalative LC50/4 h 5,320 mg/l (mouse)
84-74-2 dibutyl phthalate
Oral LD50 8,000 mg/kg (rat)
Dermal LD50 20,000 mg/kg (rabbit)
108-88-3 toluene
Oral LD50 5,000 mg/kg (rat)
Dermal LD50 12,124 mg/kg (rabbit)
Inhalative LC50/4 h 5,320 mg/l (mouse)
84-74-2 dibutyl phthalate
Oral LD50 8,000 mg/kg (rat)
Dermal LD50 20,000 mg/kg (rabbit)
Eye contact
irritating effect
Skin contact
No irritant effect.
Ingestion
No irritant effect.
Inhalation
No irritant effect.
Toxicity and irritation
IARC (International Agency for Research on Cancer)
108-88-3 toluene 3
67-63-0 propan-2-ol 3
108-88-3 toluene 3
67-63-0 propan-2-ol 3
12. ECOLOGICAL INFORMATION
Ecotoxicity
No further relevant information available
Persistence and degradability
No further relevant information available
Bioaccumulative potential
No further relevant information available
Other adverse effects
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
13. DISPOSAL CONSIDERATIONS
General information
Must not be disposed of together with household garbage. Do not allow product to reach sewage system
Disposal must be made according to official regulations.
Disposal must be made according to official regulations.
14. TRANSPORT INFORMATION
ADG label required
HAZCHEM
For safety reasons unsuitable extinguishing agents: Water with full jet
UN Number
UN1993
Proper shipping name
FLAMMABLE LIQUID, N.O.S. (ETHYL ACETATE, TOLUENE)
Transport hazard class
CLASS 3
Packing group
PG II
Environmental hazard
Not applicable
Special precautions for users
Warning: Flammable liquids
Additional information
· Quantity limitations On passenger aircraft/rail: 5 L
On cargo aircraft only: 60 L
· Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 mL
Maximum net quantity per outer packaging: 500 mL
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E2
On cargo aircraft only: 60 L
· Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 mL
Maximum net quantity per outer packaging: 500 mL
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E2
15. REGULATORY INFORMATION
Poisons Schedule Number
· TSCA (Toxic Substances Control Act):
123-86-4 n-butyl acetate ACTIVE
141-78-6 ethyl acetate ACTIVE
108-88-3 toluene ACTIVE
9004-70-0 CELLULOSE NITRATE (PARLODION) ACTIVE
1338-51-8 Toluenesufonamide ACTIVE
84-74-2 dibutyl phthalate ACTIVE
9004-36-8 Cellulose Acetate Butyrate ACTIVE
67-63-0 propan-2-ol ACTIVE
· Hazardous Air Pollutants
108-88-3 toluene
84-74-2 dibutyl phthalate
Chemicals known to cause reproductive toxicity for females:
84-74-2 dibutyl phthalate
Chemicals known to cause reproductive toxicity for males:
84-74-2 dibutyl phthalate
Chemicals known to cause developmental toxicity:
108-88-3 toluene
84-74-2 dibutyl phthalate
EPA (Environmental Protection Agency)
108-88-3 toluene II
84-74-2 dibutyl phthalate D
· TLV (Threshold Limit Value established by ACGIH)
108-88-3 toluene A4
67-63-0 propan-2-ol A4
123-86-4 n-butyl acetate ACTIVE
141-78-6 ethyl acetate ACTIVE
108-88-3 toluene ACTIVE
9004-70-0 CELLULOSE NITRATE (PARLODION) ACTIVE
1338-51-8 Toluenesufonamide ACTIVE
84-74-2 dibutyl phthalate ACTIVE
9004-36-8 Cellulose Acetate Butyrate ACTIVE
67-63-0 propan-2-ol ACTIVE
· Hazardous Air Pollutants
108-88-3 toluene
84-74-2 dibutyl phthalate
Chemicals known to cause reproductive toxicity for females:
84-74-2 dibutyl phthalate
Chemicals known to cause reproductive toxicity for males:
84-74-2 dibutyl phthalate
Chemicals known to cause developmental toxicity:
108-88-3 toluene
84-74-2 dibutyl phthalate
EPA (Environmental Protection Agency)
108-88-3 toluene II
84-74-2 dibutyl phthalate D
· TLV (Threshold Limit Value established by ACGIH)
108-88-3 toluene A4
67-63-0 propan-2-ol A4
Other Information
16. OTHER INFORMATION
SDS preparation date
8 September 2022
Comments
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.This Safety Data Sheet (SDS) has been prepared in compliance with the Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice February 2016. It is the user's responsibility to determine the suitability of this information for adoption of necessary safety precautions. The information published in this SDS has been compiled from the publications listed in Section 16: to the best of our ability and knowledge these publications are considered accurate. We reserve the right to revise Safety Data Sheets as new information becomes available. Copies may be made for non-profit use.
This Safety Data Sheet (SDS) has been prepared in compliance with the Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice February 2016. It is the user's responsibility to determine the suitability of this information for adoption of necessary safety precautions. The information published in this SDS has been compiled from the publications listed in Section 16: to the best of our ability and knowledge these publications are considered accurate. We reserve the right to revise Safety Data Sheets as new information becomes available. Copies may be made for non-profit use.