SAFETY DATA SHEET
Cobalt Napthenate
1. IDENTIFICATION
Product Identifiers
Product Name:
Cobalt Napthenate
Other Names:
Not available.
Product Number(s):
12500, 12501, EMS12500, EMS12501
CAS Number:
Not available.
Recommended use of the chemical and restriction on use
Laboratory chemicals
Company Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
Emergency Contact Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
GHS02 Flame
Flam. Liq. 3 H226 Flammable liquid and vapour.
GHS08 Health Hazard
Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Carc. 2 H351 Suspected of causing cancer.
STOT RE1 H371 Causes damage to the central nervous system through prolonged or repeated exposure.
Asp. Tox. 1 H304 May be fatal if swallowed and enters airways.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Flam. Liq. 3 H226 Flammable liquid and vapour.
GHS08 Health Hazard
Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Carc. 2 H351 Suspected of causing cancer.
STOT RE1 H371 Causes damage to the central nervous system through prolonged or repeated exposure.
Asp. Tox. 1 H304 May be fatal if swallowed and enters airways.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Label Elements
Signal Words
Danger
Hazard Statement(s)
Hazard-determining components of labelling:
Naphthenic acids, cobalt salts
Solvent naphtha (petroleum), medium aliph.
Flammable liquid and vapour.
Causes skin irritation.
Causes serious eye irritation.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
Suspected of causing cancer.
Causes damage to the central nervous system through prolonged or repeated exposure.
May be fatal if swallowed and enters airways.
Naphthenic acids, cobalt salts
Solvent naphtha (petroleum), medium aliph.
Flammable liquid and vapour.
Causes skin irritation.
Causes serious eye irritation.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
Suspected of causing cancer.
Causes damage to the central nervous system through prolonged or repeated exposure.
May be fatal if swallowed and enters airways.
Precautionary Statement(s)
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Do not breathe dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Contaminated work clothing should not be allowed out of the workplace.
Wear protective gloves/protective clothing/eye protection/face protection.
Wear respiratory protection.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Do not breathe dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Contaminated work clothing should not be allowed out of the workplace.
Wear protective gloves/protective clothing/eye protection/face protection.
Wear respiratory protection.
Primary route(s) of entry
Not available.
Human Health
Inhalation:
If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER/doctor.
Ingestion:
immediately call a POISON CENTER/doctor. Do NOT induce vomiting.
Eyes:
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. continue rinsing. If eye irritation persists: Get medical advice/attention.
Skin:
(or hair) Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. Take off contaminated clothing and wash it before reuse. If skin irritation or rash occurs: Get medical advice/attention.
Environment
In case of fire: Use for extinction: CO₂, powder or water spray.
Store in a well-ventilated place. Keep cool.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Store in a well-ventilated place. Keep cool.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Name
CAS No.
Content (w/w)
Classification
Naphthenic acids, cobalt salts
61789-51-3
>50-≤100%
Mixtures
Solvent naphtha (petroleum), medium aliph
64742-88-7
>25-≤50%
Mixtures
4. FIRST AID MEASURES
Ingestion
If symptoms persist consult doctor.
Inhalation
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
In case of unconsciousness place patient stably in side position for transportation.
Skin Contact
Immediately wash with water and soap and rinse thoroughly.
Eye Contact
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
Other Information
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
5. FIREFIGHTING MEASURES
Suitable extinguishing equipment
CO₂, sand, extinguishing powder. Do not use water.
HAZCHEM
For safety reasons unsuitable extinguishing agents: Water with full jet.
Special protective equipment and precautions for fire fighters
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Environmental precautions
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/surface or ground water.
Do not allow to enter sewers/surface or ground water.
Methods and materials for containment and clean up
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents.
7. HANDLING AND STORAGE
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Prevent formation of aerosols.
Keep ignition sources away - Do not smoke.
Protect from heat.
Protect against electrostatic charges.
Keep respiratory protective device available.
Open and handle receptacle with care.
Prevent formation of aerosols.
Keep ignition sources away - Do not smoke.
Protect from heat.
Protect against electrostatic charges.
Keep respiratory protective device available.
Conditions for safe storage
Protect from heat and direct sunlight.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Standards
Engineering controls
Keep away from foodstuffs, beverages, and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
Personal protective equipment
Eye and face protection
Tightly sealed goggles.
Skin protection
Wear protective gloves. The glove material has to be impermeable and resistant to the product/the substance/the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Body protection
Not available.
Respiratory protection
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
9. PHYSICAL AND CHEMICAL PROPERTIES
General information
Appearance
Fluid, coloured according to product specification.
Odour
Characteristic.
pH
not determined.
Vapour Pressure
6.6hPa
Density
0.9675g/cm³
Boiling Point
220°C
Melting Point
Undetermined
Solubility
Not miscible or difficult to mix.
Specific Gravity of Density
Not available.
Flash Point
40°C
Flammable (Explosive) Limits
Lower: 0.6 Vol%
Upper: 6.5 Vol%
Upper: 6.5 Vol%
Ignition Temperature
265°C
Formula
Not available.
10. STABILITY AND REACTIVITY
Reactivity
No further relevant information available.
Chemical stability
No decomposition if used according to specifications.
Possibility of hazardous reactions
No dangerous reactions known.
Conditions to avoid
No further relevant information available.
Incompatible materials
No further relevant information available.
11. TOXICOLOGICAL INFORMATION
Acute effects
64742-88-7 Solvent naphtha (petroleum), medium aliph.
Oral LD50 >6500mg/kg (rat)
Dermal LD50 >3000mg/kg (Rabbit)
Inhalative LC50/4h >14mg/l (rat)
Oral LD50 >6500mg/kg (rat)
Dermal LD50 >3000mg/kg (Rabbit)
Inhalative LC50/4h >14mg/l (rat)
Eye contact
Irritating effect.
Skin contact
Irritant to skin and mucous membranes. Sensitisation possible through skin contact.
Ingestion
Not available.
Inhalation
Sensitisation possible through inhalation.
Toxicity and irritation
Harmful
Irritant
Carcinogenic
Irritant
Carcinogenic
12. ECOLOGICAL INFORMATION
Ecotoxicity
Very toxic for fish.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Other adverse effects
Water hazard class 3: extremely hazardous for water.
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Very toxic for aquatic organisms.
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Very toxic for aquatic organisms.
13. DISPOSAL CONSIDERATIONS
General information
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Disposal must be made according to official regulations.
Disposal must be made according to official regulations.
14. TRANSPORT INFORMATION
ADG label required
HAZCHEM
For safety reasons unsuitable extinguishing agents: Water with full jet.
UN Number
UN1300
Proper shipping name
1300 TURPENTINE SUBSTITUTE solution, ENVIRONMENTALLY HAZARDOUS.
Transport hazard class
Class 3 Flammable liquids.
Packing group
III
Environmental hazard
Product contains environmentally hazardous substances: Naphthenic acids, cobalt salts.
Marine pollutant: Yes (DOT)
Symbol (fish and tree)
Marine pollutant: Yes (DOT)
Symbol (fish and tree)
Special precautions for users
Warning: Flammable liquids.
Hazard identification number (Kemler Code): 30
EMs Number: F-E,S-E
Stowage Category: A
Hazard identification number (Kemler Code): 30
EMs Number: F-E,S-E
Stowage Category: A
Additional information
Limited quantities (LQ) 5L
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30mL
Maximum net quantity per outer packaging: 1000mL
Transport category: 3
Tunnel restriction code: D/E
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30mL
Maximum net quantity per outer packaging: 1000mL
Transport category: 3
Tunnel restriction code: D/E
15. REGULATORY INFORMATION
Poisons Schedule Number
None of the ingredients is listed.
Other Information
Workers are not allowed to be exposed to the hazardous carcinogenic materials contained in this preparation. Exceptions can be made by the authorities in certain cases.
A Chemical Safety Assessment has not been carried out.
A Chemical Safety Assessment has not been carried out.
16. OTHER INFORMATION
SDS preparation date
14 February 2023
Comments
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.
This Safety Data Sheet (SDS) has been prepared in compliance with the Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice February 2016. It is the user's responsibility to determine the suitability of this information for adoption of necessary safety precautions. The information published in this SDS has been compiled from the publications listed in Section 16: to the best of our ability and knowledge these publications are considered accurate. We reserve the right to revise Safety Data Sheets as new information becomes available. Copies may be made for non-profit use.