SAFETY DATA SHEET
Hydrogen peroxide Solution, 30%
1. IDENTIFICATION
Product Identifiers
Product Name:
Hydrogen peroxide Solution, 30%
Other Names:
Hydrogen peroxide Solution, 30% (Perhydrol TM) for analysis EMSURE ISO
Product Number(s):
16790, 16792, 26212-02, EMS16790, EMS16792, EMS26212-02
CAS Number:
7722-84-1
Recommended use of the chemical and restriction on use
Laboratory chemicals.
Company Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
Emergency Contact Details
ProSciTech Pty Ltd
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
11 Carlton Street
KIRWAN QLD 4817
Australia(07) 4773 9444www.proscitech.com
2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
GHS03 Flame over circle
Ox. Liq. 2 H272 May intensify fire; oxidiser.
GHS05 Corrosion.
Skin Corr. 1A H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Acute Tox. 4 H332 Harmful if inhaled.
STOT SE 3 H335 May cause respiratory irritation.
Ox. Liq. 2 H272 May intensify fire; oxidiser.
GHS05 Corrosion.
Skin Corr. 1A H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Acute Tox. 4 H332 Harmful if inhaled.
STOT SE 3 H335 May cause respiratory irritation.
Label Elements
Signal Words
Danger
Hazard Statement(s)
May intensify fire; oxidiser.
Harmful if swallowed.
Harmful if inhaled.
Causes severe skin burns and eye damage.
May cause respiratory irritation.
Harmful if swallowed.
Harmful if inhaled.
Causes severe skin burns and eye damage.
May cause respiratory irritation.
Precautionary Statement(s)
Keep away from heat.
Keep/store away from clothing/combustible materials.
Take any precaution to avoid mixing with combustibles.
Do not breathe dusts or mists.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/protective clothing/eye protection/face protection.
Keep/store away from clothing/combustible materials.
Take any precaution to avoid mixing with combustibles.
Do not breathe dusts or mists.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/protective clothing/eye protection/face protection.
Primary route(s) of entry
Not available.
Human Health
Inhalation:
Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Ingestion:
Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. Do NOT induce vomiting.
Eyes:
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
Skin:
(or hair) Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse.
Environment
In case of fire: Use CO₂, powder or water spray for extinction.
Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Name
CAS No.
Content (w/w)
Classification
Not Available
Not Available
4. FIRST AID MEASURES
Ingestion
Call for a doctor immediately.
Drink plenty of water and provide fresh air. Call for a doctor immediately.
Drink plenty of water and provide fresh air. Call for a doctor immediately.
Inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
In case of unconsciousness place patient stably in side position for transportation.
In case of unconsciousness place patient stably in side position for transportation.
Skin Contact
Immediately wash with water and soap and rinse thoroughly.
Eye Contact
Rinse opened eye for several minutes under running water. Then consult a doctor.
Other Information
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
5. FIREFIGHTING MEASURES
Suitable extinguishing equipment
Use fire extinguishing methods suitable to surrounding conditions.
HAZCHEM
No further relevant information available.
Special protective equipment and precautions for fire fighters
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Environmental precautions
Dilute with plenty of water.
Do not allow to enter sewers/surface or ground water.
Do not allow to enter sewers/surface or ground water.
Methods and materials for containment and clean up
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Use neutralising agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Use neutralising agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
7. HANDLING AND STORAGE
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Protect from heat.
Protect from heat.
Conditions for safe storage
Keep container tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Standards
Material
TWA ppm
TWA mg/m3
STEL ppm
STEL mg/m3
Hydrogen Peroxide Solution, 30%
1ppm
1.4mg/m³
-
Engineering controls
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Personal protective equipment
Eye and face protection
Tightly sealed goggles.
Skin protection
Protective gloves. The glove material has to be impermeable and resistant to the product/the substance/the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Body protection
Protective clothing.
Respiratory protection
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
9. PHYSICAL AND CHEMICAL PROPERTIES
General information
Appearance
Clear liquid.
Odour
Odourless
pH
Not determined
Vapour Pressure
31hPa
Density
1.1g/cm³
Boiling Point
108 °C
Melting Point
-33 °C
Solubility
Fully miscible
Specific Gravity of Density
Not available
Flash Point
Not applicable.
Flammable (Explosive) Limits
Not determined
Ignition Temperature
Not determined
Formula
Not available.
10. STABILITY AND REACTIVITY
Reactivity
No further relevant information available.
Chemical stability
No decomposition if used according to specifications.
Possibility of hazardous reactions
No dangerous reactions known.
Conditions to avoid
No further relevant information available.
Incompatible materials
No further relevant information available.
11. TOXICOLOGICAL INFORMATION
Acute effects
No further relevant information available.
Eye contact
Strong caustic effect.
Skin contact
Strong caustic effect on skin and mucous membranes.
Ingestion
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of oesophagus and stomach.
Inhalation
No sensitising effects known.
Toxicity and irritation
No further relevant information available.
12. ECOLOGICAL INFORMATION
Ecotoxicity
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Other adverse effects
Water hazard class 1: slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
Must not reach sewage water or drainage ditch undiluted or unneutralised.
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
Must not reach sewage water or drainage ditch undiluted or unneutralised.
13. DISPOSAL CONSIDERATIONS
General information
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Disposal must be made according to official regulations.
Recommended cleansing agents: Water, if necessary together with cleansing agents.
Disposal must be made according to official regulations.
Recommended cleansing agents: Water, if necessary together with cleansing agents.
14. TRANSPORT INFORMATION
ADG label required
HAZCHEM
No further relevant information available.
UN Number
UN2014
Proper shipping name
2014HYDROGEN PEROXIDE, AQUEOUS SOLUTION
Transport hazard class
Class 5.1 Oxidising substances
Label: 5.1+8
Label: 5.1+8
Packing group
II
Environmental hazard
Not applicable.
Special precautions for users
Warning: Oxidising substances.
Hazard identification number (Kemler code): 559
EMS Number: F-H,S-Q
Segregation groups: Peroxides
Stowage Category: D
Stowage Code: SW1 Protected from sources of heat.
Segregation code:
SG16 Stow "separated from" class 4.1
SG59 Stow "separated from" SGG14-permanganates.
SG72 See 7.2.6.3.2.
Hazard identification number (Kemler code): 559
EMS Number: F-H,S-Q
Segregation groups: Peroxides
Stowage Category: D
Stowage Code: SW1 Protected from sources of heat.
Segregation code:
SG16 Stow "separated from" class 4.1
SG59 Stow "separated from" SGG14-permanganates.
SG72 See 7.2.6.3.2.
Additional information
ADG
Limited quantities (LQ) 1L
Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30mL
Maximum net quantity per outer packaging: 500mL
Transport category: 2
Tunnel restriction code: E
IMDG
Limited quantities (LQ) 0
Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
Limited quantities (LQ) 1L
Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30mL
Maximum net quantity per outer packaging: 500mL
Transport category: 2
Tunnel restriction code: E
IMDG
Limited quantities (LQ) 0
Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
15. REGULATORY INFORMATION
Poisons Schedule Number
S5, S6, S10
Other Information
A Chemical Safety Assessment has not been carried out.
16. OTHER INFORMATION
SDS preparation date
16 November 2023
Comments
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.
This Safety Data Sheet (SDS) has been prepared in compliance with the Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice February 2016. It is the user's responsibility to determine the suitability of this information for adoption of necessary safety precautions. The information published in this SDS has been compiled from the publications listed in Section 16: to the best of our ability and knowledge these publications are considered accurate. We reserve the right to revise Safety Data Sheets as new information becomes available. Copies may be made for non-profit use.